粤北佛冈岩体中粒斑状花岗岩地球化学、年代学及地质意义     

郭敏  黄孔文 《华南地质与矿产》2019,35(2):158-170

佛冈岩体是南岭地区最大的复式岩基,主体岩性为中粒斑状黑云母二长花岗岩,近期在佛冈岩体北缘新发现了大型离子吸附型稀土矿床。对佛冈花岗岩岩石样品进行了LA-ICP-MS锆石U-Pb定年,得出结晶年龄分别为160.5±2.9Ma、161.9±2.6Ma和164.5±2.4Ma,表明岩体形成于中晚侏罗世。岩体具有高硅、富碱富铝的特征(K2O/Na2O=1.48~2.17,A/CNK=1.05~1.27),属钙碱性过铝质钾玄质花岗岩;富集Rb、Th、U、K、Pb、Nd、Zr和Hf等元素,亏损Ba、Nb、Ta、La、Ce、Sr、P和Ti等元素,具明显的负Eu异常(δEu=0.17~0.41)。初步研究结果表明,佛冈岩体主体由上地壳砂-泥质岩在高温条件下部分熔融而成,是陆壳改造型(即S型)花岗岩,形成于古太平洋板块向欧亚板块俯冲的构造背景。  相似文献   

Genesis of the Xiuwenghala Gold Deposit in the Beishan Orogen,Northwest China: Evidence from Geology,Fluid Inclusion,and H–O–S–Pb Isotopes     

Qisong Wang  Jing Zhang  Sunping Shu  Chunkit Lai  Bowen Xu  Haiwei Sun 《Resource Geology》2019,69(2):211-226

The Xiuwenghala gold deposit is located in the Beishan Orogen of the southern Central Asian Orogenic Belt. The vein/lenticular gold orebodies are controlled by Northeast‐trending faults and are hosted mainly in the brecciated/altered tuff and rhyolite porphyry of the Lower Carboniferous Baishan Formation. Metallic minerals include mainly pyrite and minor chalcopyrite, arsenopyrite, galena, and sphalerite, whilst nonmetallic minerals include quartz, chalcedony, sericite, chlorite, and calcite. Hydrothermal alterations consist of silicic, sericite, chlorite, and carbonate. Alteration/mineralization processes comprise three stages: pre‐ore silicic alteration (Stage I), syn‐ore quartz‐chalcedony‐polymetallic sulfide mineralization (Stage II), and post‐ore quartz‐calcite veining (Stage III). Fluid inclusions (FIs) in quartz and calcite are dominated by L‐type with minor V‐type and lack any daughter mineral‐bearing or CO₂‐rich/‐bearing inclusions. From Stages I to III, the FIs homogenized at 240–260°C, 220–250°C, and 150–190°C, with corresponding salinities of 2.9–10.9, 3.2–11.1, and 2.9–11.9 wt.% NaCl eqv., respectively. The mineralization depth at Xiuwenghala is estimated to be relatively shallow (<1 km). FI results indicate that the ore‐forming fluids belong to a low to medium‐temperature, low‐salinity, and low‐density NaCl‐H₂O system. The values decrease from Stage I to III (3.7‰, 1.7–2.4‰, and ?1.7 to 0.9‰, respectively), and a similar trend is found for their values (?104 to ?90‰, ?126 to ?86‰, and ?130 to ?106‰, respectively). This indicates that the fluid source gradually evolved from magmatic to meteoric. δ³⁴S values of the hydrothermal pyrites (?3.0 to 0.0‰; avg. ?1.1‰) resemble those of typical magmatic/mantle‐derived sulfides. Pyrite Pb isotopic compositions (²⁰⁶Pb/²⁰⁴Pb = 18.409–18.767, ²⁰⁷Pb/²⁰⁴Pb = 15.600–15.715, ²⁰⁸Pb^/204Pb = 38.173–38.654) are similar to those of the (sub)volcanic ore host, indicating that the origin of ore‐forming material was mainly the upper crustal (sub)volcanic rocks. Integrating evidence from geology, FIs, and H–O–S–Pb isotopes, we suggest that Xiuwenghala is best classified as a low‐sulfidation epithermal gold deposit.  相似文献   

In Situ U‐Th‐Pb Dating and Sr‐Nd Isotope Analysis of Bastnäsite by LA‐(MC)‐ICP‐MS     

Yue‐Heng Yang  Fu‐Yuan Wu  Qiu‐Li Li  Yamirka Rojas‐Agramonte  Jin‐Hui Yang  Yang Li  Qian Ma  Lie‐Wen Xie  Chao Huang  Hong‐Rui Fan  Zi‐Fu Zhao  Cheng Xu 《Geostandards and Geoanalytical Research》2019,43(4):543-565

Bastnäsite is the end member of a large group of carbonate–fluoride minerals with the common formula (REE) CO₃F·CaCO₃. This group is generally widespread and, despite never occurring in large quantities, represents the major economic light rare earth element (LREE) mineral in deposits related to carbonatite and alkaline intrusions. Since bastnäsite is easily altered and commonly contains inclusions of earlier‐crystallised minerals, in situ analysis is considered the most suitable method to measure its U‐Th‐Pb and Sr‐Nd isotopic compositions. Electron probe microanalysis and laser ablation (multi‐collector) inductively coupled plasma‐mass spectrometry of forty‐six bastnäsite samples from LREE deposits in China, Pakistan, Sweden, Mongolia, USA, Malawi and Madagascar indicate that this mineral typically has high Th and LREE and moderate U and Sr contents. Analysis of an in‐house bastnäsite reference material (K‐9) demonstrated that precise and accurate U‐Th‐Pb ages could be obtained after common Pb correction. Moreover, the Th‐Pb age with its high precision is preferable to the U‐Pb age because most bastnäsites have relatively high Th rather than U contents. These results will have significant implications for understanding the genesis of endogenous ore deposits and formation processes related to metallogenic geochronology research.  相似文献   

古地下水定年新方法——81Kr法     

凌新颖  马金珠  杨欢  于海超  何建华 《地质与资源》2019,28(1):90-94

由于⁸¹Kr化学性质稳定、半衰期长且在地下水运移过程中没有额外来源的优点,近年来,成为测定古老地下水年龄（10⁵~10⁶ a）的有效手段.国外对于⁸¹Kr的测定方法、地下水定年应用研究已较为深入,而国内应用⁸¹Kr作为水文地质学的研究尚处于起步阶段.本文通过对国内外⁸¹Kr应用于地下水测年的原理以及⁸¹Kr的测定方法进行总结,针对目前研究的问题进行探讨,并对今后放射性氪核素在水文地球化学中的研究进行展望,为国内对于⁸¹Kr的测定与在古地下水定年研究方面提供科学依据.  相似文献   

大兴安岭北段巴升河岩体锆石U-Pb年代学及其地质意义     

陈会军  崔天日  钱程  李林川  陈井胜  李伟  吴新伟  江斌  司秋亮  秦涛  唐振  张渝金  郭威 《地质与资源》2019,28(5):405-412

大兴安岭北段扎兰屯地区巴升河岩体由碱长花岗岩组成.采用LA-ICP-MS方法对碱长花岗岩开展锆石U-Pb测年,结果为297.8±3.6 Ma,岩体形成于早二叠世.该岩体4个样品的全岩地球化学等特征显示：巴升河岩体中碱长花岗岩具有富Si、高K、富碱的特征,属于弱过铝质钾玄岩系列,同时,样品∑REE偏高,Eu负异常明显,富集大离子亲石元素,具有A型花岗岩特征,综合前人研究成果及同位素年代学特征,认为兴安地块与松嫩地块拼合的时间早于298 Ma.  相似文献   

LA-ICP-MS标准锆石原位微区U-Pb定年及微量元素的分析测定     

栾燕  何克  谭细娟 《地质通报》2019,38(7):1206-1218

利用长安大学成矿作用及其动力学实验室Agilent 7700X四极杆等离子体质谱(ICP-MS)和Photo Machines Analyte Excite 193nm激光,在激光频率为5Hz,束斑直径为35μm条件下,对91500、GJ-1、Ple?ovice和Qinghu 4个标准锆石进行了原位微区U-Pb同位素和微量元素测定。结果显示,91500标准锆石20个测试点的~(206)Pb/~(238)U年龄范围为1059~1070Ma,~(206)Pb/~(238)U年龄加权平均值为1063.8±6.6Ma;GJ-1标准锆石28个测试点的~(206)Pb/~(238)U年龄范围为601~610Ma,~(206)Pb/~(238)U年龄加权平均值为605.4±3.0Ma;Ple?ovice标准锆石28个测试点的~(206)Pb/~(238)U年龄范围为336~341Ma,~(206)Pb/~(238)U年龄加权平均值为338.8±1.4Ma;Qinghu标准锆石40个测试点的~(206)Pb/~(238)U年龄范围为158~165Ma,~(206)Pb/~(238)U年龄加权平均值为159.9±0.7Ma。上述结果表明,91500、GJ-1、Ple?ovice和Qinghu 4个标准锆石的~(206)Pb/~(238)U年龄都在误差范围内,且年龄加权平均值与前人报道的年龄在误差范围内一致。同时,4个标准锆石的微量元素结果基本落在前人文献报道的范围内。从4个标准锆石的稀土元素球粒陨石标准化曲线可以看出,稀土元素的相对含量较准确。以上结果表明,建立的测试方法实现了对锆石原位微区U-Pb定年及微量元素的同时测定,分析数据结果准确、可靠。  相似文献   

新疆东昆仑西段库拉甫河岩组火山岩地球化学特征及锆石U-Pb年龄     

周能武  陈邦学  杨有生  郭新成  朱志新  陈甜  白权金 《地质通报》2019,38(5):757-766

对东昆仑西段库拉甫河岩组火山岩地球化学进行研究,结果显示,主量元素MgO、FeO含量较高,TiO_2和K_2O含量分别为1.12%、0.63%,与岛弧拉斑玄武岩(0.84%、0.43%)接近;微量元素具有Sr富集,高场强元素Nb、Ta略亏损,P无明显分馏或未分馏的特征,稀土元素球粒陨石标准化配分曲线显示良好的同源性(配分曲线变化规律近似一致),且与富集型洋脊玄武岩配分趋势一致。结合构造环境判别,认为其形成于岛弧环境,具有岛弧拉斑玄武岩的特征,来源于与岛弧相关的富集地幔。利用锆石U-Pb测年获得2组年龄,其中一组年龄为688.7±5.1Ma,代表捕获晶年龄,另一组年龄483.4±3.3Ma为结晶年龄,代表玄武岩的形成年龄,属于早奥陶世。结合其构造环境、岩石地球化学特征和年龄数据,认为其是原特提斯洋俯冲消减环境下的产物,且原特提斯洋俯冲至少持续到早奥陶世。  相似文献   

Comment on: Mass Fractions of Forty‐Six Major and Trace Elements,Including Rare Earth Elements,in Sediment and Soil Reference Materials Used in Environmental Studies. Fiket et al. (2017), Geostandards and Geoanalytical Research, 41, 123–135     

Vibor Roje 《Geostandards and Geoanalytical Research》2019,43(2):317-327

This paper is intended to be a constructive discussion of Fiket et al. (2017, Geostandards and Geoanalytical Research , 41 , 123–135), who dealt with the determination of major, trace and rare earth elements in several sediment and soil certified reference materials. In the present author's view, the paper by Fiket et al. (2017) suffers from a lack of reference to several publications in which somewhat similar results had already been reported. The present contribution therefore provides a comparison of previously published results with those of Fiket et al. for the CRMs soil NCS DC 77302 (GBW 07410), stream sediment NCS DC 73309 (GBW 07311), marine sediments MESS‐3 and NCS DC 75301 (GBW 07314) and estuarine sediment IAEA‐405. It is argued that this fuller consideration (a) allows critical evaluation of the quality of the results presented by Fiket et al. and (b) highlights the advantages of their work. Finally, attention is drawn to the (possible or real) problems that can arise during simultaneous determination of multiple trace elements.  相似文献   

河北赞皇杂岩官都群碎屑沉积岩锆石SHRIMPU-Pb定年及其地质意义   总被引：1，自引：0，他引：1  

张帆  王彦斌  杨崇辉  杜利林  苑鸿庆 《地质通报》2019,38(8):1335-1343

新太古代—古元古代表壳岩系在华北克拉通广泛发育,在赞皇地区也出露有较典型的中低级变质的火山-沉积岩系,即从原赞皇群解体出来的官都群,其形成时代和成因目前仍有争议。官都群的主要岩石组合为变基性火山岩(包括角闪片岩和斜长角闪岩)、大理岩、石英片岩,以及一系列长英质副片麻岩等。对其中的长英质副片麻岩进行碎屑锆石定年研究,并结合前人已报道的碎屑锆石数据可知,碎屑锆石年龄主要峰值约为2.5Ga,部分样品出现2.0～2.2Ga的峰值。变质锆石记录主要有2个范围,分别为2.48Ga左右和1.85～1.9Ga,可能代表了2期不同的构造热事件记录。结合该地区近年来的研究,可以得到如下认识:(1)样品中存在形态完好的长柱状锆石,表明是近源沉积;(2)约2.48Ga的变质记录与核部岩浆锆石的年龄(约2.5Ga)非常接近,可能代表了物源区中酸性岩体侵位后遭受的一次构造热事件,而不代表沉积岩形成后遭受变质的记录,即沉积过程晚于2.48Ga;(3)官都群至少有一部分岩石组合形成于古元古代;(4)官都群可能是不同时代、不同岩性单元拼贴而成,需要进一步解体。  相似文献   

Tectonic evolution of the West Kunlun Orogenic Belt along the northern margin of the Tibetan Plateau:Implications for the assembly of the Tarim terrane to Gondwana   总被引：2，自引：0，他引：2  

Chuan-Lin Zhang  Hai-Bo Zou  Xian-Tao Ye  Xiang-Yan Chen 《地学前缘(英文版)》2019,10(3):973-988

The West Kunlun orogenic belt(WKOB) along the northern margin of the Tibetan Plateau is important for understanding the evolution of the Proto-and Paleo-Tethys oceans. Previous investigations have focused on the igneous rocks and ophiolites distributed mostly along the Xinjiang-Tibet road and the China-Pakistan road, and have constructed a preliminary tectonic model for this orogenic belt. However, few studies have focused on the so-called Precambrian basement in this area. As a result, the tectonic affinity of the individual terranes of the WKOB and their detailed evolution process are uncertain. Here we report new field observations, zircon and monazite U-Pb ages of the "Precambrian basement" of the South Kunlun terrane(SKT) and the Tianshuihai terrane(TSHT), two major terranes in the WKOB. Based on new zircon U-Pb age data, the amphibolite-facies metamorphosed volcanosedimentary sequence within SKT was deposited during the late Neoproterozoic to Cambrian(600-500 Ma), and the flysch-affinity Tianshuihai Group, as the basement of the TSHT, was deposited during the late Neoproterozoic rather than Mesoproterozoic. The rock association of the volcano-sedimentary sequence within SKT suggests a large early Paleozoic accretionary wedge formed by the long-term lowangle southward subduction of the Proto-Tethys Ocean between Tarim and TSHT. The amphibolitefacies metamorphism in SKT occurred at ca. 440 Ma. This ca. 440 Ma metamorphism is genetically related to the closure of the Proto-Tethys Ocean between Tarim and the Tianshuihai terrane, which led to the assembly of Tarim to Eastern Gondwana and the final formation of the Gondwana. Since the late Paleozoic to early Mesozoic, the northward subduction of the Paleo-Tethys Ocean along the HongshihuQiaoertianshan belt produced the voluminous early Mesozoic arc-signature granites along the southern part of NKT-TSHT. The Paleo-Tethys ocean between TSHT and Karakorum closed at ca. 200 Ma, as demonstrated by the monazite age of the paragneiss in the Kangxiwa Group. Our study does not favor the existence of a Precambrian basement in SKT.  相似文献